EXIF data in TIFF (and other files based on TIFF, like Nikon RAW and many others) is tree structured. Actually TIFF data is tree structured, with EXIF just being one node in the tree. For example, here is the meta-data dump from one of the RAW files directly from my camera:
TIFF image file directory 1, 27 entries:
New subfile type: 1 (reduced)
image_width = 160
image_length = 120
bits_per_sample, count 3:
8 8 8
Compression: 1 (none)
Photometric interpetation: 2 (RGB)
make = "NIKON CORPORATION"
model = "NIKON D3S"
strip_offsets = 118478
orientation = 1
samples_per_pixel = 3
rows_per_strip = 120
strip_byte_counts = 57600
x_resolution = 300.00
y_resolution = 300.00
Planar configuration: 1 (whole pixels together)
Resolution unit: 2 (inch)
software = "Ver.1.01"
date_time = "2012:08:12 11:43:03"
artist = ""
subIFD, count 2:
176320 176440
reference_black_white, count 6:
0.0000 255.00 0.0000 255.00 0.0000 255.00
Copyright: ""
EXIF IFD = 600
EXIF exposure time: 4.00 ms, 1/250 s
EXIF aperture: f/8.00
EXIF exposure program ID: 3 (Aperture priority)
EXIF film speed iso: 400
EXIF date/time original: 2012:08:12 11:43:03
EXIF date/time digitized: 2012:08:12 11:43:03
EXIF APEX exposure bias: 0.00
EXIF APEX max lens aperture: f/4.00
EXIF metering mode ID: 5 (Pattern)
EXIF light source type ID: 0 (Unknown)
EXIF flash status: 0000h
Did not fire
No strobe return detetction function
Flash mode unknown
Flash function present
No red-eye reduction mode or unknown
EXIF lens physical focal length: 40.0 mm
EXIF manufacturer info, length 117346:
78 105 107 111 110 0 2 16 ...
EXIF user comment, character set ASCII:
EXIF sec fraction date/time: 0.140
EXIF sec fraction date/time original: 0.140
EXIF sec fraction date/time digitized: 0.140
EXIF sensing method ID: 2 (One-chip color area sensor)
EXIF file source equipment type ID: 3 (Digital still camera)
EXIF scene type ID: 1 (Directly photographed)
EXIF sensor color pattern, 2 x 2:
red grn
grn blu
EXIF custom rendering ID: 0 (Normal)
EXIF exposure mode ID: 0 (Auto)
EXIF white ballance ID: 0 (Auto)
EXIF digital zoom ratio: 1.00
EXIF 35mm equivalent focal length: 40 mm
EXIF scene capture type ID: 0 (Standard)
EXIF gain control ID: 1 (Low gain up)
EXIF applied contrast ID: 0 (Normal)
EXIF applied saturation ID: 0 (Normal)
EXIF applied sharpness ID: 0 (Normal)
EXIF distance range ID: 0 (Unknown)
GPS info IFD = 176078
GPS version: 2,2,0,0
GPS latitude reference: N
GPS latitude: 33.00000 deg 22.7547 min 0.0000 sec, = 33.37924
GPS longitude reference: W
GPS longitude: 113.00000 deg 30.9130 min 0.0000 sec, =-113.51522
GPS altitude reference: 0
GPS altitude: 412.0 meters (1351 feet)
GPS time: 18.00 43.00 3.00 (18:43:03.000 UTC)
GPS sat: 08
GPS map datum:
GPS date: 2012:08:12
Original creation date/time: 2012:08:12 11:43:03
TIFF/EP version ID: 1.0.0.0
Reading subdirectory at 176320, 8 entries:
New subfile type: 1 (reduced)
Compression: 6
x_resolution = 300.00
y_resolution = 300.00
Resolution unit: 2 (inch)
jpeg_interchange_fmt = 179968
jpeg_interchange_fmt_len = 1545395
ycbcr_positioning = 2
Reading subdirectory at 176440, 17 entries:
New subfile type: 0 (normal image)
image_width = 4288
image_length = 2844
bits_per_sample = 14
Compression: 1 (none)
Photometric interpetation: 32803 (CFA, color filter array)
strip_offsets, count 407:
1725376 1785408 1845440 1905472 1965504 2025536 2085568 2145600 ...
samples_per_pixel = 1
rows_per_strip = 7
strip_byte_counts, count 407:
60032 60032 60032 60032 60032 60032 60032 60032 ...
x_resolution = 300.00
y_resolution = 300.00
Planar configuration: 1 (whole pixels together)
Resolution unit: 2 (inch)
CFA repeating pattern size: 2 x 2
CFA pattern, count 4:
red grn
grn blu
Sensor layout type: 2 (1-chip color area)
TIFF data is stored in "directories" or "IFDs", which can be tree structured. My program that dumps this information uses indentation to show the tree structure. Note how all the EXIF data is in one directory (IFD), and the GPS info added because I had a GPS receiver attached when the picture was taken in another separte IFD.
The TIFF and EXIF tags are standard and documented out there. Sometimes manufacturers add their own private information using private tags. Notice the "EXIF manufacturer info" tag. That is Nikon proprietary, and contains some color ballance information apparently.