The speed of optical vs. Radioversus radio has much more to do with delays and latencies in camera and flash electronic systems, than the type of waves traveling between the systems.
EM waves are so fast as to have no effect at typical photography exposure times. To know the speed differences of any system you have to know the electronic specs of each, radio or optical. I doubt the detalsdetails of such are published by most manufacturers, but they would know best (ifif you can get them to devulge )divulge.