I assume you mean their bosom, not their chests. First?
Firstly, some reactions to other answers. I: I would be careful about wider angle lenses as it makes them look less attractive in general.
Poses and clothing can do a lot. And using a model with a bigger bosom helps a lot, too. However, post editing is often applied in the professional world. In photoshopPhotoshop, liquify [LINK] can be used, and some free software havehas similar tools. That type is most often seen used to thin the chins and waistlines of the models (there's a wide range of videos showing how to make a jane doeJane Doe look like a "supermodel" - often used by women on facebook to fight low self-esteem).
I once made a video on how to use that kind of tool in the opposite way [LINK].
And used it to show that the pick for wonder woman isn't so bad as people claim (includes bosom enlargement, but it is a bit roughly done - I made it for a nerd page as a joke):